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discombobulate (informal) to confuse or disconcert.
discountenance to embarrass or disconcert. [1/2 definitions]
embarrass to shame, disconcert, make ill at ease, or make painfully self-conscious. [1/5 definitions]
faze to bewilder or to disturb the composure or shake the resolve of; disconcert or daunt.
unnerve to deprive of composure, courage, determination, or the like; disconcert; discourage.